Solvent effects on the molecular recognition of anions.
نویسندگان
چکیده
Anion recognition of two flexible diols in different solvents and binary mixtures were examined. Binding constants (K) in CD3CN and CDCl3 are surprisingly similar, and CD3CN-solvent mixtures led to reduced values of K that are smaller than in either pure solvent. A surprising U-shaped dependence is observed.
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عنوان ژورنال:
- Chemical communications
دوره 49 99 شماره
صفحات -
تاریخ انتشار 2013